Oxygen Nonstoichiometry of the Copper-Substituted Lanthanum Cobaltite LaCo0.9Cu0.1O3-δ
نویسندگان
چکیده
منابع مشابه
Thermodynamics of the ( lanthanum + strontium + copper + oxygen ) high - T , superconductors I
The subambient heat capacities of three (SrO),(CuO), inter-oxide samples with Y = y = I: I = 7. y=l; and u=l. y=2, were measured as a part of an investigation into the chemical thermodynamics of the high-T, superconducting system (lanthanum + strontium + copper + oxygen). No anomalous contribution to the heat capacity was observed over the experimental region. The heat capacity of the Sr,,Cu,,O...
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The oxygen nonstoichiometry of La0 8Sr0 3CoO3 has been determined as a function of oxygen partial pressure and temperature using a high-temperature coulometric titration cell. For each measured value of the oxygen chemical potential, the oxygen nonstoichiometry is found to be nearly independent of temperature. The equilibrium partial energy and entropy associated with oxygen incorporation have ...
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La0.6Sr0.4CoO3 d thin films of varying thicknesses (20–170 nm) were prepared by pulsed laser deposition on yttria-stabilized zirconia (100) substrates, and their electrochemical electrode performance was correlated with the chemical surface composition and microstructure (e.g. porosity, surface area). The surface cation composition was analyzed by an atomic etching procedure with on-line induct...
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Methods and models describing oxygen diffusion and desorption in oxides have been developed for slightly defective and well crystallised bulky materials. Does nanostructuring change the mechanism of oxygen mobility? In such a case, models should be properly checked and adapted to take into account new material properties. In order to do so, temperature programmed oxygen desorption and thermogra...
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ژورنال
عنوان ژورنال: ECS Proceedings Volumes
سال: 1999
ISSN: 0161-6374,2576-1579
DOI: 10.1149/199919.0424pv